Synchronize Pro Rapidshare If I Download A Movie From ITunes, Can I Copy It My Zune Collection And Synchronize It To My Zune?

If I download a movie from iTunes, Can I copy it my Zune collection and synchronize it to my Zune? - synchronize pro rapidshare

I would like to hire download (k) a movie on iTunes. Can I file on my Windows side of my MacBook Pro and a copy in my library and sync your Zune and watch it on my Zune?